Pig
irons are produced by blast furnaces from iron ore and from ferrous scrap in
cupolas or electric furnaces (refined pig irons), or as by-products from other
processes such as vanadium or titanium oxide production. These latter pig irons
are usually high purity irons most suitable for ductile iron production.
The
composition of refined pig irons can be adjusted to comply with customer
requirements, including a known residual content or added alloys with a
specified range of alloy content.
Typical
pig iron compositions, with the exception of high purity irons, are shown in
Exhibit M.
Control
Pig
iron is ordered to a given specification range and should be accompanied by a
supplier’s certificate of composition which should include the major residual
contents.
No
two batches are the same and unless the operation can withstand a reasonable
tolerance in casting compositional range, each batch (which in the case of
blast furnace irons may have variations in the batch) should be kept separate.
This ideal may not be possible in large melting plants.
Foundries
should insist on a certificate of analysis and also carry out analytical checks
to ensure a quality material.
Pig iron is an expensive metallic and should be used as a general
quality control in the metallic charge, i.e.:
provide and even out carbon “pick-up” variations
provide and even out silicon levels
control phosphorus levels
ensure a better mixing in cupola operations which have inadequate wells and
fore hearth facilities
as a control for excessive residual element levels and possible gas levels when
high steel charges are used.
Return Scrap
The
return scrap of each individual foundry should be of a known and generally
consistent composition. It should be used to the maximum consistent with
obtaining the desired composition of the castings to be manufactured.
Control
Each
grade of scrap should be kept separate. Large pieces should be broken to a size
suitable for individual furnace requirements.
c) Ferro-Alloys
Ferro
alloys are used as additions to ensure control of elements such as silicon and
manganese in the standard non or low alloy irons.
The high alloy irons such as Ni
hard, Ni resist and high chromium iron, represent a small percentage of the
iron foundry industry and require special attention to their choice of alloys
and ferro alloys. Ferro silicon
|
Most common grades in lump form
contain 75–80% and 45–50% silicon levels.
|
Silicon carbide
|
In lump form containing 55–60%
Si and 25–30% C
|
Ferro manganese
|
Usually obtained in lump form
and contains 75–80% manganese.
|
The
use of larger amounts of ferro silicon in cupolas can result in excessive
silicon variations unless suitable mixing volumes are provided in wells,
receivers or ladles.
Do
not rely too much on the cupola for mixing purposes as it is very possible to
obtain a wide variation in silicon content from the well, even with a tap and
bott system.
Control
Ferro
alloys should be checked that they comply with the foundry’s specification for
size, grading and composition.
In
particular, ferro silicon should be checked for fines as this is a source of
high silicon losses and hence variation in silicon content in melting
operations.
Briquettes
should be checked for consistency of weight and friability. Instability of
briquette can also lead to high silicon losses in the cupola.
In
both cases alloy content should be occasionally checked by the foundry or by an
independent laboratory.
Accurate weighing of ferro alloy additions on suitable scales is
an absolute essential to control silicon and manganese contents. When
briquettes are used, ensure the chargers can count!