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Wednesday, 9 August 2017
Monday, 7 August 2017
TYPES OF CORE COATING
1. Brushing and Swabbing
Brushing and swabbing methods of applying
coatings are used in many foundries. The effort imparted by brushing helps to
force the refractory particles into the pores of the sand surface, which is a
desirable feature. The swab is a most useful aid in coating interior of
difficult pockets and re-entrant angles. Both methods give uneven thickness and
strives from brush motion is visible on casting. They also depend on the skills
of the operator. There is also the risk of sand-coating mixture due to frothing
and this ini-tiates metal penetration .
2. Spraying
Spraying is a much faster means of
application widely used in foundries of all types. It is important to pay
greater attention to the coating composition because less me-chanical effort is
available to force the particles into the pores between the sand grains.
Selection of the solid constituents and the overall viscosity is more critical
for sprayed coating than for brushing and swabbing. Spray methods use specially
designed guns to atomize the coating into a fine spray. This method along with
brushing suffers the disability of not being able to coat deep re-cesses
thoroughly. One reason for this is the back pressure of air which prevents
refractory deposition in the cavity. The system of airless spraying provides a
means of overcoming this disadvantage. Airless Spray has higher transfer
efficiency and lower chance of blowback. Again, it is more efficient when a
flat surface is involved which is also placed vertically during spraying.
The above discussion refers to liquid
coating mixture however, a group of
researchers from Austria developed a new method of spraying dry coating on
substrates over-coming the inherent disadvantages of the use of wet coating.
The process is called electrostatic or tribostatic powder spraying method, also
designated as EPS method. In this process, the surfaces of the substrate is
first made conductive (if it is not a conducting material) by spraying
electrically conducting polymer solutions on them. Then the powder coatings can
be applied. According to the developers, this novel coating process has been
tested on all popular binder systems—from
cold box, through hot box and furan to inorganic types .
3.
Dip Coating
Dip
coating techniques can be described as a process where the substrate to be
coated is immersed in the liquid or coating and then withdrawn with a
controlled speed under controlled temperature and atmospheric conditions.
Coating thickness increases with a faster withdrawal speed. The deposited
thickness is determined by the bal-ance of forces at the stagnation point on
the coating sus-pension surface. The faster the withdrawal speed the more
coating suspension is pulled up onto the substrate surface because there is no
time for the suspension to flow back down to the coating pool. During sol-gel
dip coating, the coating suspension is rapidly concentrated on the surface of
the substrate by gravitational draining with associated evaporation and
condensation reactions. Dip coating is usually used for cores and is well suited
for automatic applications. Dip coating enhances a high production rate and
high transfer efficiency (almost 100%) and relatively little labour is
required. The effectiveness of dip coating depends greatly on the viscosity of
the coating, which thickens with ex-posure to air unless it is carefully
managed. The viscosity of the coating must remain practically constant if the
deposited film quality is to remain high and the same. To maintain viscosity,
solvent must be routinely added as makeup. This results in high volatile
organic compounds (VOC). Dip coating is not suitable for objects with hol-lows
or cavities . Other factors that determine the effectiveness of dip coating
include coating density and surface tension. Better surface penetration is obtained
than with spraying because of the head pressure of the coating in the dip tank.
Even thickness of surface is necessary so as to maintain dimensional accuracy
and true reproduction of contour. Uneven coating is at its worst when it runs
down as tears. This defect can be encouraged by the nature of the surface to be
coated but is mainly due to the kind of the suspension agent used in the
coating. Tears and similar coating faults are sources of high gas evolution and
cast-ing defects may result. The coating can be cured by a number of methods
such as conventional thermal, UV, or IR techniques depending on the coating
formulation
4.
Flow Coating
Flow
coating is a method of applying a refractory coating that can be described as
wetting the moulds or heavy cores with a garden hose at low pressure. With flow
coating the mould or core is maneuvered so it is at an angle (20 to 40° to the
vertical) in front of the operator and
coating applied through a hose, starting at the top and in lateral movements
progressively working down to the bottom. Flow coating is usually used for
large or oddly shaped parts that are difficult or impossible to dip coat.
Coatings applied by flow coating have only a poor to fair appearance unless the
parts are rotated during drip-page. Flow coating is fast and easy, requires
little space, involves relatively low installation cost, requires low
maintenance, and has a low labour requirement. Required operator skill is also
low. Flow coating achieves a high coating transfer efficiency, often 90% and
higher. Prin-cipal control of dry-film thickness depends on the coating
viscosity. Flow coating can eliminate all the various problems associated with
the other coating techniques such as spraying, dipping or brushing. For flow
coating to be effective, it must create a surface and sub-surface coating.
Surface coating provides a barrier to the metal and improves surface finish.
The sub-surface coating penetrates the surface of a mould or core to fill the
voids between the sand
grains. This reduces the possibility of metal penetration and veining
Flow coating method, it is seen that the mould is
inclined at an angle.
5. Drying of Coating
After coating
application, each coating must be ‘dried’, which means that the suspension
agent (water, alcohol or volatile agents) must be completely removed. These
sub-stances do penetrate the mould or core material and do not have any
protective effect for the mould or core. On the contrary, it can cause severe
problems of gas forma-tion, blows, slag entrapment, porosity, blistering, and
penetration and drastically reduce the strength of the mould or core. The
methods of removal are different depending on the type of coating.
5.1. Drying Organic Solvent-Based Coatings
In the past, foundries typically used
solvent-based carri-ers because they dry quickly without external heating (air
drying). They are also referred to as self-drying coatings. This takes a lot of
time. Consequently, flame torching became the accepted means of drying coated
cores and moulds. However, workplace environmental, health and safety concerns,
as well as economic consid-erations emanating from the rapidly increasing cost
of petrochemicals based solvent, continue to enhance the development and use of
water-based coating technolo-gies .
5.2. Drying Water-Based Coatings
The
trend today is towards water-based coatings. But they require longer drying
times using air drying and conventional ovens compared to organic solvent-based
coatings. The drying temperature must exceed 100°C, but lower than the
temperature at which the binder system is destroyed (mostly 250°C).Different
drying tech-niques such as high intensity lights, microwave, drying tunnels and
infrared ovens can be applied to water-based coatings. It was reported in [40]
that the high intensity lights and drying tunnels did not dry fast enough as
ex-pected to prevent coatings from dripping and losing thickness uniformity.
Microwave drying used non-selec- tive heat that penetrated the sand cores and
caused them to disintegrate. Infrared ovens, however, dry the coated cores or
moulds quickly without damaging the sand bod-ies. Application of infrared
heating for mould and core coating can reduce drying time by 85%. The energy
sav-ing comes from the controllability of the infrared unit, which brings the
mould surface to the desired tempera-ture and then cycles off in a
predetermined time sequence. Less heat is dissipated to the surroundings. The
infrared elements direct the heat more effectively at the mould and can dry
deep cavities and mould pockets – thus con-tributing to better casting quality.
The sub-surface of the mould is not affected. An additional advantage of using
infrared heating is that only 25% of the floor space occu-pied by the resistance
oven was required. A signifi-cant development in water-based coatings is the
feature in which there is a distinctive colour change as the coat-ing dries and
transitions from the wet to the dry state as shown in Figure. This
change in colour offers visual confirmation that the coating is dry. Not only
that this shows when drying is complete, it can also serve as a quality control
tool. When drying takes longer time than necessary it will mean that the
moisture content is high and can be adjusted. This feature saves energy used in
drying thereby saving cost.
CHARACTERIZATION OF COATINGS
Characterization of Coatings
In order to understand the behaviour of coatings contain-ing refractory materials, there is need for characterization of the coatings. The parameters that characterize foundry coatings are discussed below.
6.1. Specific Gravity
Specific gravity is the unit weight per unit volume. Spe-cific gravity is a quick test that allows inferences to be drawn about the total solids and refractory components present in the coating . The knowledge of the spe-cific gravity of the suspension agent and that of the re-fractory material is critical. There would be no difficulty in keeping the refractory material in permanent suspen-sion in the suspension agent if they have similar specific gravity . The specific gravity also gives a fair idea of the refractory material content of the coating. Water has a lower specific gravity of 1. When it used to dilute a coating with relatively higher specific gravity component; the specific gravity of the coating is reduced.
2. Viscosity
Viscosity, a measurement of material flow properties, is the best test for evaluating coatings because of its high correlation with the dried deposit on the core. There are several different methods of measuring viscosity. The most commonly applied in foundries is the flow cup method as shown. The flow cup measure of viscosity requires the use of a cup with a specific size of hole in the bottom to match the material being used. A stopwatch is used as the cup is lowered into the coating and then taken from the surface of the coating after it has filled. The time it takes the coating to drain through the hole is the viscosity in number of second
3. Baume´ Parameter
The Baume´ test is the most common test used in foun-dries to control coating because it is quick and easy. The test is performed with a hydrometer. It usually consists of a thin glass tube closed at both ends, with one end enlarged into a bulb that contains fine lead shot or mer-cury. The glass tubular end contains a calibrated scale in degrees Baume. The Baume scale of numbers relates to the specific gravity and body of a coating. After mixing the coating sample thoroughly, the hydrometer is imme-diately floated in the coating slurry. When it stops sink-ing, the degrees Baume is read directly from the hy-drometer scale. Baume is a simple test to help measure dilution consistency. However, there is a poten-tial for operator variability, and test parameters must be carefully controlled. Operator consistency in placing the hydrometer into the coating and length of test time are critical. When Baume test is used in combination with the specific Gravity measured by Gravimetric method, the combined results can be a more useful diagnostic tool. Many metal casting facilities also include viscosity test in their refractory coating control test procedures . L.
Winardi et al., reported that coating viscosity is typically reported in degree Baume. Higher Baume´ number indicates higher viscosity.
It was also reported in that Baume when per-formed in a controlled laboratory environment tracks well certain coating properties.
6.4. Solid content
The solids in the coating must be measured because they are the refractory materials that provide protection to the core or mould. The higher the percent solids, the more protection the coating offers. The solid content of a coat-ing determines some other important parameters of the coating such as the density, viscosity, thickness, cover-age etc. Therefore, the knowledge of the amount of solid in the coating is very important for reproducibility of these properties. The percent solid content can be de-termined by dividing the weight of the dried coating by the original weight and multiplying by 100.
6.5. Colloidal Stability
Colloidal stability is describing the formation of uniform suspension of the particles in the coating matrix. The stability of particles is determined by their resistance to aggregation.
The formation of uniform suspensions of particles can be understood by calculation of the sedimentation rates assuming that the particles are spherical so that Stokes’s Law may be applied. Equating gravitational and fric-tional forces:
The stability of small particles is surprising, since sur-face tension leads to very high pressure differences across surfaces with small radii of curvature. For a parti-cle of radius r, density ρ, and relative molar mass M, with surface tension γ, the pressure difference across the curved surface, pr, compared to that across a flat surface, po, is given by the Kelvin equation.
Thus small particles should tend to dissolve while lar-ger particles should grow as observed in Oswald ripening of precipitates.
6.6. Coating Thickness
Coating thickness is usually measured using a destructive test. To date no reliable non-destructive test is being ap-plied by the foundry industry to measure the consistency of the coating layer thickness applied on the cores or moulds. In some tests, the cores are sectioned and the measurements were taken using a microscope.
In some other methods, the coating is removed from a flat surface on a core and the difference in the cored sur-face and the coated surface is measured.
The amount of surface deposit can be used as a refer-ence for future comparisons and making decisions about coating allowance in casting design. There is a strong correlation between the viscosity of the coating and the coating thickness. However, coating dry thick-ness has proved difficult to measure, so what is generally done is to measure the wet coating layer thickness using the elcometer wet film “comb” as shown in Figure 10. The elcometer wet film combs can be used in accordance with following standards; ISO 2808-7B, ASTM D 4414-A, BS 3900-C5-7B and NF T30-125. The film combs have various lengths on their sides. These stan-dards specify that wet film comb be perpendicular to the substrate and the thickness of the coating lies between the biggest value wet tooth and the smallest value dry tooth values . The wet coating layer thickness will be correlated to the dry coating thickness, if the volume to solids ratio of the coating is known . As a rule of thumb dry coating thickness is 50% of the wet coating thickness.
In dip coating, the coating thickness is mainly defined by the withdrawal speed, the solid content (density), the surface tension and the viscosity of the liquid. The coat-ing thickness can be calculated from landau-Levich equation. This equation gives the wet coating layer thickness on a vertically withdrawn flat plate.
where hw = Wet coating thickness
υ = withdrawal speed
ρ = density
γLV = Liquid-vapour surface tension
g = acceleration due to gravity
To calculate the dry film thickness these equations need to be modified. It was reported in [51], that Yan et al. derived Eq. (4) for dry film thickness, hd
6.7. Coating Penetration Depth
The distance the coating penetrates the core is an impor-tant feature to a coating’s success. A coating that lies entirely on the surface of the cores is not anchored well and will most likely spall away. A coating that penetrates too much will over degrade the core. Coating penetration is also a function of core density. A core that is blown too tightly resists coating penetration, while one blown softly acts like a sponge and absorbs much water. There-fore, any evaluation of coating penetration should be done on a core that is of normal production quality. It is also note worthy that core release agents may waterproof the core and affect coating penetration. Coating penetra-tion is evaluated by cutting a coated dried core and ob-serving how far the coating penetrates the core. The usual reference is sand grain penetration. A normal level of penetration is 2 – 4 sand grains . It was reported in, that this is not the most precise methodology be-cause sand grain sizes differ from one foundry to the other. Moreover, a batch of foundry sand has a known distribution of a variety of grain sizes within it, which also makes using sand grain count as a measuring system inadequate. Lower surface tension increases the depth of coating penetration. As coating penetration increases, the thickness of the proud layer decreases while the reverse is the case if the proud layer increases. Thermal ex- pansion increases with the thickness of the proud coating layer (the layer on the surface of the substrate). Therefore, an optimum proud layer thickness is needed to reduce the expansion defects on the casting made with these cores. This requires that the coating penetration depth is controlled.
6.8. Coating Permeability
Coating permeability is the amount of gas that can pass through the coating. The level of permeability is detected by both the type and amount refractory materials that are used in the coating formulation and the dry film thick-ness deposit on the core. The permeability of the coating on the core is measured using a laboratory permmeter. A coating with low permeability is desirable when directing evolved gases to vent through specific areas of the core. A high permeability coating is best when the goal is the evacuation of core gases through the coating. The per-meability of the coating at the coating-metal interface may be different than that measured on the core. Some constituents of the coating may quickly thermally de-compose leaving voids that result in higher permeability. Some may soften and flux resulting in lower permeabil-ity. High permeability coating will reduce the time required for removing the degradation products and will increase the metal fill velocity, often leading to blister and fold defects. Low permeability coating will slow down the metal velocity, which causes the molten metal to lose the adequate thermal energy required for com-plete pyrolysis, traps the degradation products and leads to misrun or partial fill. It has been reported in that mould filling times decreased with permeability of the coatings. A standard approach to characterize the per-meability of porous materials is to use Darcy’s law (Eq. 8), which relates volumetric flow and pressure gradients with the properties of the fluid and porous materials
small Reynolds number (Re). The upper limit is at a value of Re between 1 and 10. At a high Reynolds num-ber, the deviation from Darcy’s law will be observed. The Darcian permeability coefficient K indicates the ca-pability of the porous medium to transmit fluids. Theo-retically, the permeability coefficient only depends on the porous medium’s properties. At high pressures, the turbulent and inertia flow become more dominant so that Darcy’s law is no longer valid. The transition from the linear (Darcy’s law) to the nonlinear regime°Ccurs gradually as the Reynolds number increases. Therefore, the classical approach to macroscopically characterize the effect of inertia and turbulence on flow through real porous media is to use Forchheimer’s equation (Eq. 9), which includes parabolic parts in the equation consider-ing the influence of inertia and turbulence
where V = fluid velocity averaged over the total cross-section of the porous specimen (Q/A)
β = inertial parameter
ρ = density of the fluid
This equation macroscopically quantifies the non-linear effect. Research has shown that the deviation from Darcy’s law (which occurs at Re = 1 – 10) cannot be attributed to turbulence, and inertia forces are more appropriate to explain the deviation. The role of inertial effects over such a transition at high Re from linear to nonlinear flow in the pore space was success-fully simulated in the laminar regime without including turbulence effects However, the random aspect of the pore distribution induces a highly heterogeneous lo-cal flow which becomes turbulent at high Reynolds’ re-gimes
Core Degradation
Core degradation varies from coating to coating. The longer a core stays wet, the more core degradation will take place. So, it is the best practice to put cores into an oven heat zone as quickly as possible after the core is coated. Most coatings use surfactants as wetting agents to allow the coating to penetrate the proper depth. These surfactants change the surface tension of the water, mak-ing it worse for core degradation. To evaluate the effect refractory coating on core strength, dip one set of cores and leave the other set undipped. Place both sets in the drying oven until dry and allow them to cool to ambient temperature approximately one hour. Then, when cool, evaluate both sets of cores for strength. The comparative loss in strength of coated cores will most likely be sub-stantial. It was reported in that the strength of core and mould material will decrease about 30% with This is in agreement with the authors’ findings in the investigation of the strength of core materials. The pub-lication of these results is on the way.
6.10. Wettability and Surface Tension
The deposition of a coating on a solid substrate generates new interface between dissimilar materials and involves considerations of wettability, spreading, interface evolu-tion and adhesion. The wettability of a solid by a liquid is characterized in terms of the angle of contact that the liquid makes on the solid. The basic law governing the equilibrium of a liquid drop on a surface was formu-lated by Thomas Young σ.
The drop is shaped by the resultant forces pulling at the three-phase contact line of the drop, where the solid/liquid, liquid/gas and solid/gas interfaces meet, in the plane of the solid as shown in Figure 11. The forces (per unit length) acting at this line are the surface ten-sions and their balance yields the famous Young’s equa-tion.
where σSG , σSL and σLG are solid/gas, solid/liquid and liquid/gas surface tensions, respectively
According to Taylor’s depiction of liquid droplet shape on solid surface, the droplet height, h = 2asin (θ*/2), where a is the capillary length (a = (σ/ρg)1/2, σ, the liquid surface tension and ρ, its density, a = 2.7 mm for water). It shows that gravity g can affect drop shape be-sides the three phase forces. Only if the drop is small enough that the effect of gravity is negligible, which typically is the case for drops of millimetre size down to micrometres, the drop will have the shape of a spherical cap and the liquid/gas interface meets the solid surface at an angle θc, which is called the contact angle of a flat surface . The condition θ < 90° indicates that the solid is wetted by the liquid, such a surface is referred to as a hydrophilic surface and θ > 90° indicates nonwetting, and the surface is called a hydrophobic surface. Wet-tability of a solid surface is governed by the chemical properties and the microstructure of the surface. Wet-tability is mainly determined by its interfacial free energy (σSG). The greater, the free surface energy, the easier, the liquid can spread upon and vice versa.
Young’s equation applies to ideal surfaces that are perfectly smooth and devoid of all chemical and struc-tural inhomogeneities. The contact angle measured on a rough surface (called the Wenzel angle, θw) does not obey Young’s equation; it is related to the equilibrium (Young’s) angle θy , by Equation (11)
where r is the ratio of true wetted area to the apparent area. Equation (11) is called the Wenzel equation.
Wenzel’s equation applies to equilibrium angles on rough surfaces and not to advancing and receding angles of a droplet on a rough solid surface that give rise to contact-angle hysteresis. Hysteresis, H, is defined as the difference of the advancing and receding angles (i.e., H = θa - θr) and arises because the liquid-vapour interface does not retrace its original path when it recedes on the solid, so that spreading is thermodynamically irreversible. Because roughness hinders the contact line motion by creating energy barriers, the system can reside in any of the po-tential wells accessible to it that are commensurate with the vibrational (or thermal) energy of the droplet. In many industrial processes like that found in foun-dries, the substrate (core in foundries) is immersed in a liquid coating material, and then withdrawn to leave a liquid film on the substrate. The film (coating) thickness depends upon the surface tension, withdrawal speed, substrate geometry, roughness, and viscosity. The dis-persion of fine, granular solids in a liquid vehicle is a basic step in preparing paints and other coating materials and involves particle transfer across a gas-liquid interface. The transfer of non-wettable solids into liquids requires the solid to overcome a surface energy barrier at the liq-uid-gas interface, and energy must be expended to assist the transfer of non-wettable solids. Once the solid enters the liquid, the capillary (attractive) forces and gas bridges between solids control such phenomena as agglomeration, dispersion, and air entrapment. The inter-particle forces between dispersed solids are due to liquid surface tension and pressure difference across the curved liquid-vapour boundary between contacting solids. The maximum in-ter-particle force, F, due to capillary forces between two touching spheres where R is the radius of the sphere. The force increases with increasing liquid surface tension and decreasing contact angle and particle radius. These forces affect the viscosity, density, and sedimentation behaviour of the suspension and the properties.
Saturday, 5 August 2017
METANOIA—A SHIFT OF MIND
When you ask people about what it is like being
part of a great team, what is most striking is the meaningfulness of the
experience. People talk about being part of something larger than themselves,
of being connected, of being generative. It becomes quite clear that, for many,
their experiences as part of truly great teams stand out as singular periods of
life lived to the fullest. Some spend the rest of their lives looking for
ways to recapture that spirit.
The most accurate word in Western culture to
describe what happens in a learning
organization is one that hasn't had much
currency for the past several hundred years. It
is a word we have used in our work with
organizations for some ten years, but we always
caution them, and ourselves, to use it sparingly
in public. The word is "metanoia" and it means a shift of mind. The word has a rich history. For
the Greeks, it meant a fundamental shift or change, or more literally transcendence ("meta"—above or beyond,
as in "metaphysics") of mind ("noia," from the root "nous," of mind). In the
early (Gnostic) Christian tradition, it took on aspecial meaning of awakening shared intuition
and direct knowing of the highest, of God.
"Metanoia" was probably the key term
of such early Christians as John the Baptist. In the
Catholic corpus the word metanoia was eventually
translated as "repent."
To grasp the meaning of "metanoia" is
to grasp the deeper meaning of "learning," for learning also involves a fundamental shift or movement of
mind. The problem with talking about "learning organizations" is that the
"learning" has lost its central meaning in contemporary usage.
Most people's eyes glaze over if you talk to
them about "learning" or "learning organizations."
Little wonder—for, in everyday use, learning has
come to be synonymous with "taking in
information." "Yes, I learned all
about that at the course yesterday." Yet, taking in information is only distantly related to real learning. It
would be nonsensical to say, "I just read a great book about bicycle riding—I've now learned
that." Real learning gets to the heart of what it means
to be human. Through learning we re-create ourselves. Through learning we become
able to do something we never were able to do. Through learning we reperceive the world
and our relationship to it.Through learning we extend our capacity to
create, to be part of the generative process of life. There is within each of us a deep
hunger for this type of learning. It is, as Bill O'Brien of Hanover Insurance says, "as fundamental
to human beings as the sex drive." This, then, is the basic meaning of a
"learning organization"—an organization that is continually expanding its capacity to create its
future. For such an organization, it is not enough merely to survive. "Survival
learning" or what is more often termed "adaptive learning" is important—indeed it is
necessary. But for a learning organization, "adaptive learning" must be joined by
"generative learning," learning that enhances our capacity to create.
A few brave organizational pioneers are pointing
the way, but the territory of
building learning organizations is still largely
unexplored. It is my fondest hope that this
book can accelerate that exploration.
THE PRICE MUST BE PAID BY EVERYONE
In Straight Talk for Monday Morning,
Allan Cox observed, "You have to give up something to be a member of a
team. It may be a phony role you've assigned to yourself, such as the guy who
talks too much, the woman who remains silent, the know-it-all, the know nothing,
the hoarder of talented subordinates, the non-sharer of some resource such as
management information systems (MIS), or whatever. You give up something, to be
sure, such as some petty corner of privilege, but you gain authenticity in
return. The team, moreover, doesn't quash individual accomplishment; rather it
empowers personal contributions." People who've never had the experience
of being on a winning team often fail to realize that every team member
must pay a price. I think some of them think that if others work hard, they can
coast to their potential. But that is never true. If everyone doesn't pay the
price to win, then everyone will pay the price by losing.
2. The Price Must Be Paid All the Time
Many people have what I call
"destination disease." Some people mistakenly believe that if they
can accomplish a particular goal, they no longer have to grow. It can happen
with almost anything: earning a degree, reaching a desired position, receiving
a particular award, or achieving a financial goal. But effective leaders cannot
afford to think that way. The day they stop growing is the day they forfeit
their potential—and the potential of their organization. Remember the words of
Ray Kroc: "As long as you're green, you're growing. As soon as you're
ripe, you start to rot."Destination disease is as dangerous for a team as
it is for any individual. It makes us believe that we can stop working, stop striving,
stop paying the price—yet still reach our potential. But as Earl Blaik, former
football coach at the United States Military Academy, observed, "There is
no substitute
for work. It is the price of
success." That truth never goes away. That's why President Dwight D.
Eisenhower remarked, "There are no victories at bargain prices." If
you want to reach your potential, you can never let up.
3.The Price Increases If the Team Wants
to Improve, Change, or Keep Whining
Have you ever noticed how few
back-to-back champions there are in sports? Or how few companies stay at the
top of Forbes magazine's lists for a decade? Becoming a champion has a
high price. But remaining on top costs even more. And improving upon your best
is even more costly. The higher you are, the more you have to pay to make even
small improvements. World-champion sprinters improve their times not by seconds,
but by hundredths of a second. No one can move closer to his or her potential
without paying in some way to get there. If you want to change professions, you
have to get more education, additional work experience, or both. If you want to
run a race at a faster pace, you must pay by training harder and smarter. If
you want to increase earnings from your investments, you either put in more money
or take greater risks. The same principle applies to teams. To improve, change,
or keep winning, as a group the team must pay a price, and so must the
individuals on it.
4. The Price Never Decreases
Most people who quit don't give up at
the bottom of the mountain, they stop halfway up it. Nobody sets out with the
purpose of losing. The problem is often a mistaken belief that a time will come
when success will suddenly get cheaper. But life rarely works that way. When it comes to the Law
of the Price Tag, I believe there are really only two kinds of teams who violate it:
those who don't realize the price of success, and those who know the price but are not willing
to pay it. No one can
force a team member to have the will to succeed. Each member must decide in his or her own
heart whether the goal is worth
the price that must be paid. But every
person ought to know what to expect to pay in order for a team to succeed. For
that reason, I offer the following observations about the cost of being part of
a winning team. To become team players, you and your teammates will have at
least the following required of you .
• Sacrifice: There can be no success
without sacrifice. James Allen observed, "He who would accomplish little
must sacrifice little; he who would achieve much must sacrifice much."
When you become part of a team, you may be aware of some of the things you will
have to give up. But you can be sure that no matter how much you expect to give
for the team, at some point you will be required to give more. That's the
nature of teamwork. The team gets to the top only through the sweat, blood, and
sacrifice of its team members Time Commitment: Teamwork does not come cheaply.
It costs you time—that means you pay for it with your life. It takes time to
get to know people, to build relationships with them, to learn how you and they
work together.
• Personal Development: The only way
your team will reach its potential is if you reach your potential.
That means today's ability is not enough. Or, to put it the way leadership
expert Max DePree did: "We cannot become what we need to be by remaining
what we are." That desire to keep striving, to keep getting better, is a key
to your own ability, but it is also crucial for the betterment of the team.
That is why UCLA's John Wooden, a great team leader and the greatest college
basketball coach of all time, said, "It's what you learn after you know it
all that counts."
• Unselfishness: People naturally look
out for themselves. The question "What's in it for me?" is never far
from their thoughts. But if a team is to reach its potential, its players must
put the team's agenda ahead of their own. And if you give your best to the
team, it will return more to you than you give, and together you will achieve
more than you can on your own. Certainly there are other prices individuals
must pay to be part of a team. You can probably list several specific ones
you've paid to be on a team. The point is that people can choose to stand on
the sidelines of life and try to do everything solo. Or they can get into the
game by being part of a team. It's a trade-off between independence and
interdependence. The rewards of teamwork can be great, but there is always a
cost. You always have to give up to go up
FOUDNRY COATIN TECHNOLOGY
Research in coatings for various applications
such as aesthetics, corrosion protection, wear resistance, thermal barrier,
self-cleaning, antifouling etc. have been very wide spread but not much is
going on in the area of foundry coatings in recent times. The use of foundry
coatings for moulds and cores during casting is very necessary as a means of
achieving high quality surface finish of castings more especially in complex
internal channels created by use of cores. This is despite the con-siderable
advances that have taken place over the recent years in binder and sand
technology giving the foundries greater opportunity to choose and control these
basic foundry raw materials. Since casting surface finish de-pends largely on
sand particle grading, it might be sup-posed that a proper selection of a
particular grade of sand would be the only requirement to achieve the desired
casting surface quality. However, there are other factors to be considered,
such as the ability to vent off the gases produced during casting, economic use
of a binder, non availability of sand with required grading, etc., these make
the use of coatings the more practicable approach .
In filling a
mould with liquid metal its surface is sub-jected to thermal, mechanical and
physicochemical ac-tions. The oxidation products of the metal, reacting with
the mould material, form low-melting materials such as silicates, which
lubricate the grains of the quartz sand well. This promotes penetration of the metal
into the in-ter-granular spaces and the formation of mechanical pick-up which
is difficult to remove from the casting surface. Considering that the sand
moulds and cores are highly porous, the production of castings in these
materi-als without pick-up and other surface defects is possible only with
protection of the surfaces of moulds and cores with refractory coatings. The
fundamental requirements for the refractory coatings are minimum porosity, high
refractoriness and reduction of the physicochemical reac-tion at the
metal-coating interface (lubrication, solution, penetration). These refractory
coatings are used to make better castings and to reduce costs. Castings
sur-face quality is improved because the coating produces smoother metal
surfaces, either by filling the spaces be-tween the sand grains or by
providing, to the metal, a surface smoother than the mould surface itself.
Further improvement from the coatings is due to the cleaner and better peel of
sand at shakeout and elimination of certain defects such as metal penetration,
veining, erosion, sand burn-in etc [3,4].
Controlling
casting quality and increasing productivity are top priorities for foundries to
become more competi-tive in a global casting market and coatings can help to
provide the required remedy. Addressing the issue of mould/core moisture can
lead to improvements in pro-ductivity and help keep foundries competitive.
Identify-ing problems like poor mould/core density and moisture in the both
core and mould is challenging, but advance- ment in coating technology enhances
the engineering of refractory coatings as a quality-control tool to help
iden-tify these issues. The presence of moisture can lead to a scrapped
casting, but coatings that indicate when drying is complete can address this
issue. Coating technologies that change colour offer visual confirmation that
the coating is dry. This confirmation may also indicate poor sand compaction in
a core or mould, as these areas will absorb more moisture from the coating and
take longer time to dry. Therefore, a visually obvious colour change based on
moisture content permits these new refractory coatings to act not only as a
barrier between the metal and the mould or core but also as a quality
diagnostic .
The objective of this paper is to collate as much as
possible the significant works and results on foundry coatings in the past and
to give insight to a novel tech-nology for the production of foundry coatings
with greater potential towards improving the surface quality of castings from
readily available raw materials at a cheaper cost. This paper provides a
detailed understanding of the constitution of foundry coatings while providing
alterna-tives to the foundry coating components depending on the metal to be
cast and their properties and compatibility with sand properties such as grain
size and grain size distribution and binder properties.
Groups of Foundry Coatings
Foundry coatings may be divided into two
groups, those applied dry and those applied wet.
2.1. Coatings for Dry Application
For dry application, the most widely used
is Plumbago. Other dry coatings used to a lesser extent include mica, white
talc and wheat flour. These materials are either shaken or blown onto mould or
core surfaces from open-mesh cloth bags. Plumbago is a finely ground blend of
graphite containing 80% to 90% of particles that will pass through a 200-mesh
(75 micron). The graphite may be amorphous (no definite crystal structure) or
crystalline (having definite particle shape or flaky). Graphite will not melt
at the highest foundry temperatures but its car-bon is driven off by oxidation
at these temperatures de-pending on the air (containing oxygen) available at
the metal-mould interface. Amorphous graphite oxidizes easier than does
crystalline graphite. Plumbago is applied dry only on green sand moulds .
2.2. Coatings for Wet
Application
Mould and core coatings for wet
application are of two types, carbon-base and carbon-free coatings. Both types
are sold in either powder or paste form. The adherence of the coating on the
mould or core surface depends on the moisture in the sand. Carbon-based
coatings may contain several types of graphite, coke, anthracite or any of the
numerous combinations that can be made from these materials. Carbon-free
coatings may contain silica, mica, zircon flour, magnesite, olivine, clays,
talc or a combina-tion of these materials. Many coatings formulations con-tain
both carbonaceous and non-carbonaceous raw mate-rials to take the advantage of
the synergistic characteris-tics of both types. Foundry coatings for wet applica-tion
are also classified into two, based on their carrier systems. Those employing
an aqueous carrier and those in which organic solvent carriers are used. The
former must be dried after application while the later are self-drying or can
be ignited and dried by their own combustion. Both classes of coating make use of
the re-fractory materials .
3. Components of a Coating (Coating
Materials)
A refractory coating on the mould or core
should have the following characteristics:
Sufficient
refractory properties to cope with the metal being poured
Good adhesion to
the substrate to prevent spalling
Be permeable to
minimize air entrapment
Be fast in drying
No tendency to
blistering, cracking or scaling on dry-ing
Good suspension
and remixing properties
Minimize core
strength degradation
Provide adequate
protection against metal penetration
Good stability in
storage
Good covering
power
Good application
properties by the method chosen
Leveling well and
minimizing runs and tear drops
For a coating to achieve these
characteristics, the coating will consists of
Refractory filler
Liquid carrier
Suspension agents
(Rheology control system)
Binder agents
Additives as shown
in Figure 1
3.1. Refractory Filler (Filler Materials)
Refractory materials are
substances or minerals that have high melting points and are difficult to fuse
except at very high temperatures. They are processed at high tem-perature
and/or intended for high temperature applica-tions. Refractoriness has been
defined by Commit-tee C-8 of the American Society for Testing and Materi-als
(ASTM) as “...the capability of maintaining the desired degree of chemical and physical
identity at high temperatures and in the environment and conditions of use.”
The melting temperature of refractory materials is an important characteristic
showing the maximum tem-perature of use and represents fundamental point in
phase diagrams used in high temperature chemistry, metallurgy, ceramics etc.
In coatings,
refractory materials are dispersed in the binder and constitute the skeleton of
the coating film. They increase the density, viscosity and hardness of the
coating film and reduce the permeability.
There are
characteristics other than resistance to high temperatures that refractory
materials should exhibit. These include:
Suitable particle
shape, particle size (PS) and particle size distribution (PSD),
Chemically inert
with molten metal,
Not be readily
wetted by molten metal,
Not contain
volatile elements that produce gas on heating,
Have consistent
cleanliness and pH
Be compatible with
new chemical binders as they are developed The significance of particle shape,
PS and PSD are elaborated below in the following paragraphs. The other factors
are readily understood.
At a given
refractory material loading, particle shape determines the mechanical
properties of the coating ma-trix. The particle shape is usually described by a
dimen-sionless parameter, the aspect ratio–this is the ratio be-tween the
average diameter and average thickness of the particle. The higher the aspect
ratio of the particle of re-fractory material, the higher the reinforcing
effect on the coating matrix will be.The particle size distribution (PSD) of a
refractory material is usually given as a cumulative curve, indicat-ing the
amount per volume or weight of particles (%), which are smaller than a given
size. PSD can be adjusted by grinding and classification. The coarsest
particles act as points of highest stress concentration, where crack or
fractures occur under loading. Impact strength is signifi-cantly improved by
using finer particles .It is generally assumed that a sieve analysis sharply
defines between the different sizes of particles compris-ing aggregate
materials. According to [3], such is not the case. On any particular sieve one
finds particles ranging from those just able to pass through the preceding
sieve to those just unable to pass through to the following sieve. As a result
of this lack of sharp differentiation between the particle sizes on adjacent
sieves, it is difficult to sim-ply screen aggregate material and secure
particles of uniform size on each of two successive sieves (Figure 2).
From a practical aspect, the refractory
material should be available in large quantities at reasonable prices [8]. In
foundry coatings, refractory materials determine the efficiency of the coating.
The refractory filler may be either a single material or a blend of materials
selected for specific applications. They make up 50% to 70% of the coating.
Fillers are chosen for their particle size and shape, density, sintering point,
melting point, thermal conductivity, thermal expansion and reactivity towards
the metal being cast and the mould or core material on which it is applied
These refractory materials in-clude Plumbago, silica, graphite, coke,
anthracite, zircon flour, magnesite, Chalmette, olivine, clays, talc, chromite,
alumina, mica.The material of which sand moulds and cores are made generally
exert influence upon the surface quality of the castings formed from these
moulds and cores. This is because they have a high degree of porosity to the
extent that the pores tend to be filled with molten metal causing high surface
roughness on the castings.
Therefore, with the application of
refractory coatings on the surface of the moulds and cores that will be in
contact with the molten metal, the refractory particles tend to fill these
pores on drying, thereby creating a smooth inert surface on the moulds and
cores. These re-fractory materials have different properties and are se-lected
depending on the metal to be cast. The more common refractory materials are
discussed below.
Silica flour is a commonly used refractory filler,
par-ticularly in steel foundries. The silica flour should con-tain minimum 98%
silica and not more than 1% moisture. The fusion point of silica flour is 1734°.
At ap-proximately 650°C (1100°F), silica refractory filler has an expansion of
1.6%. Silica fillers are well known for use as pigments, reinforcing agents and
the like.
Commercially available silica and other
metals oxides are often derived from burning volatile metal halides with
various fuels and oxidants. Silica filler has been produced by direct
combustion of silicon powder as re-ported in [14]. Silica flour does not
excessively increase viscosity [15]. However, it is reported in [16] that as
the content of silica filler increased the coefficient of thermal expansion of
the composite decreased while the viscosity increased.
Zircon flour
is a highly refractory
material and is primarily used for coatings in steel foundries. Good qual-ity
zircon flour suitable for foundry work should contain minimum 64% zircon oxide
(ZrO2), 30 to 35.5% silica and maximum of 0.5% TiO2 + Fe2O3. Refractory uses of
zircon require low interstitial water content. This trans-lates into low loss
on ignition. Excessive internal radia-tion damage to zircon crystals (metamict
zircon) can cause an increase in the loss on ignition of a zircon product. The
desire of the refractory market for a low loss on ignition implies that a low
picocurie/gram re-quirement is placed on zircon products.
It has a
specific gravity of about 4.5 and a pH value of the water-based coating of not
more than 9.The melting temperature is 2727 ± 10°C . The high heat
conductivity, about double that of silica, promotes quick formation of a
solidified metal layer and helps in pro-ducing castings with a fine grained
structure. Its higher density than that of silica prevents metal penetration .
Graphite refractory materials are most commonly
used for coatings in iron foundries and for non-ferrous castings. Molten metal
does not wet graphite and sand grains coated with graphite coatings resist
metal penetra-tion. This is the reason why graphite, Plumbago and car-bon are
usually used in mould and core coatings except those for steel.Mould and core
coatings containing carbonaceous ingredients are not used for steel,
particu-larly low-carbon steels. The reason for this is because steel is
sensitive to the carbon content and if there is carbon pick-up, the properties
of the steel will change. The graphite used is naturally flaky type, silvery
white in appearance, of a fine powder form and free from gritty particles. Good
quality graphite for foundry use should have ash content of about 12 to 15%
maximum; volatile matter 3% maximum; and moisture content 1% maxi-mum. Graphite
inclusion in mould and core coatings also improves stripping during shakeout. A
highly useful, desirable, substantially non-porous, smooth, non-spalling mould
surface can be produced on porous moulds by subjecting them to a treatment with
a controlled amount of colloidal graphite suspended in a volatile carrier or
vehicle followed by a drying after the treatment and fi-nally baking at a
relatively high temperature. The mould surfaces prepared in this manner possess
substantially no pores, at least those of a size which can be penetrated by
molten metal. With the presence of pores which cannot be penetrated by molten
metal it is considered to be sub-stantially non-porous. The treatment, it is
believed, in-troduces colloidal graphite particles into the mould pores and the
subsequent baking fixes or anchors them in such a way as to prevent removal
unless the mould surface itself is worn or cut away
Olivine is orthosilicate of magnesium and iron
(MgFe)O·SiO2 and it occurs as forsterite and fayalite. Its density,
conductivity and refractoriness are higher than those of silica. Its fusion
point is high—about 1800°C- and as such it is favoured for heavy sections of
alloy steel casting. Its resistance to slag reaction makes it suitable for the
casting of high manganese steels. Olivine refrac-tory material can also be used
for the casting of non fer-rous castings of intricate nature Olivine is used in
preference to silica sand to overcome the silicosis hazard (Silicosis is
a form of respiratory disease caused by inhalation of silica dust, and is
marked by inflammation in the upper lobes of the lungs).
Talc is a hydrous magnesium silicate mineral
with the chemical formula (Mg3Si4O10·(OH)2) and the softest mineral on Mohr’s
scale of hardness. Talc is widely used as a filler material .Talc Mohr’s
hardness is 1 and density of 2.6 - 2.8 g/cm3. It is used in many industries
because of its characteristics—low hardness, adhesion capability (surface
coating), high melting temperature, chemical inertness, hydrophobic,
organophilic, platy, low electrical and high thermal conductivity . The inert
and lamellar platy natures of talc improve its cracking resistance, adhesion
and barrier properties.
Talc is
practically insoluble in water and weak acids and alkalis. Above 900°C, talc
progressively loses its hydroxyl groups and above 1050°C, it recrystallizes
into different forms of enstatite (anhydrous magnesium silicate). Talc’s
melting point is at 1500°C
Mica is a plate-like crystalline
aluminosilicate and has been widely used as reinforcing filler in polymer
matrix due to its excellent mechanical, electrical and thermal properties as
well as lower cost than carbon or glass fibres .Chemically they contain complex
silicate of aluminium and alkalis with hydroxyl. They crystallize in monoclinic
system. Some varieties may contain iron, magnesium, lithium. There are seven
important mica minerals: Muscovite or potassium mica, H2KAl3(SiO4)3; Paragonite
or sodium mica, H2NaAl3(SiO4)3; Lepidolite or lithium mica, K·Li·Al(OH,
F)2Al(SiO4)3; Phlogopite or magnesium mica, H2KMg3Al(SiO4)3; Biotite or
magne-sium iron mica, (H2K)(Mg, Fe)3Al(SiO4)3; Zinnwaldite or lithium iron
mica, Li2K2Fe2Al4Si7O24; and Lepidome-lane or iron mica, (H, K)2(Fe,
Al)4(SiO4)5. Muscovite is the commonest of all and whenever the word mica is
used it is understood to mean muscovite. No other natu-ral substance has been
found to possess the properties equal to those of mica. Of all the known varieties
of mica only muscovite and phlogopite are of commercial im-portance. Muscovite
finds the largest use while phlo- gopite has a limited application. On the
other hand phlo- gopite is superior to muscovite in heat resistance. Mus-covite
can withstand temperatures up to 700°C, and phlogopite up to about 1000°C.
Phlogopite is, therefore, preferred where a high temperature is required .Mica
can be used as refractory filler in foundry core and mould coatings to
eliminate or reduce finning defect in castings because of its lamellar
plate-like nature
Clays used for the manufacture of refractory
fillers are the kaolinites. In the kaolinites there are equal numbers of silica
and alumina sheets and equal numbers of silicon and aluminium atoms. The basic
composition is Al2O3- 2SiO2·2H2O Kaolinite crystals are normally hex-agonal
disks which are built up by laying double sheets of alumina octahedral and
silica tetrahedral on top of one another Kaolin clay is the most extensively
used particulate mineral in the filling of coating of paper .Since kaolin clay
is fine and refractory and has found application in coating for papers, it also
has poten-tial application in foundry coating technology.
Other filler
materials and their properties are provided
Different filler
materials and their functions in the ma-trix depending on their various
particles sizes are pre-sented in Figure 3.
3.2. Liquid Carrier
The liquid career is the medium
containing the coating constituents and also serves as the vehicle to transport
the filler materials onto the sand substrate Therefore, the coatings are
typically suspensions of high melting point refractories in a liquid carrier.
Liquid carrier con-stitutes about 20 to 40% of the coating. After application,
it is necessary to dry the coating to prevent gas formation when the hot metal
is poured into the mould. The forma-tion of gases may cause casting defects.
After the liquid carrier is removed by evaporation or combustion, a pro-tective
refractory layer is deposited on the surface of the mould or core .This layer
prevents or minimizes the penetration of molten metal into the sand, reduces or
prevents "burn-on" and erosion of the sand, and generally improves
the quality of a casting surface. However, there are many factors to consider with carrier
selection, in-cluding: compatibility of carrier with sand binder and/or
refractory, method of drying, flammability and “burning” characteristics;
toxicity and odour; application; labour and floor space. The most commonly used
carrier are water-based (aqueous) and spirit-based (organic solvent)
3.2.1. Aqueous-Based Carrier
In this class, water is used as the
carrier. Water is cheap and readily available but drying in an oven is usually
necessary to remove it before casting
Table 1. Other filler materials and their
respective proper-ties [17]. Data
|
Chamotte
|
Chromite
|
Magnesite
|
Chrome-
Magnesite
|
Availability
|
abundant
|
Good
|
Good
|
Good
|
Refractoriness℃
(approx.)
|
1780
|
1850
|
1850
|
1850
|
Thermal expansion
(×1000 mm/m)
|
0.0052
|
0.007
|
0.014
|
0.012
|
Thermal conductivity (WK-1m-1)
|
6-9.5
|
9-15
|
20-30
|
13-20
|
Wettability with molten
metal
|
No wetting
|
No wetting
|
No wetting
|
No wetting
|
Water is non flammable and non toxic. It
has no flash point. Water is the safest of the carriers. From environmental
view point, the use of water-based coatings is highly recommended. However,
apart from requiring heat to dry water-coatings, complete drying of deep
pockets in a reasonable time can be difficult. It has greater tendency for
tears or runs compared to organic-based coatings. It reduces the tensile
strength of urethane no-bakes, cold box and silicate sands. It increases the
potential for core breakage. There is also possible degradation during core
storage. Moreover, aqueous-based coatings can freeze
3.2.2. Organic Solvent-Based Carrier
Organic solvent-based or spirit-based
coating usually contains isopropanol (isopropyl alcohol) as liquid carrier for
coating constituents, and the coating is dried by ig-niting and burning off the
isopropanol This is typi-cal of organic solvent-based carriers which also
include methanol, ethanol, hydrocarbons and chlorinated hydro-carbons. They dry
very fast. Isopropanol is recommended for use on large moulds and cores
Isopropanol has good combustion characteristics with slow burning front and a
moderate hot flame. This reduces the chance of over-heating the sand surface
and subsequent problems of sand friability. Isopropanol is also technically
accept-able because it is compatible with a wide range of sus-pension agents
and resin binders also used in the formu-lation of these coatings. Most of the
organic sol-vent-based carriers are referred to as air-drying carrier. These
include carbon tetrachloride, methylenechloride, chloroethene and chloroform.
They rely for efficiency on a rapid rate of evaporation which places them in a
more hazardous category than isopropanol. They are also not versatile as
isopropanol in the formation of foundry coatings. In many cases, they call for
specialized forms of gelling media and resin binders The use of organic
solvent-based coatings is threatened by environmental issues because they are
toxic and flammable
3.3.
Suspension Agents (The Rheology Control
System)
There is no difficulty in keeping solid
particles in per-manent suspension in a liquid if both have the same spe-cific
gravity. This is not the case with foundry sand coatings. The maintenance of
solid particles in suspen-sion is achieved by addition of suspension agents.
These agents provide the suspension system that prevents the filler particles
from agglomerating and separating out during storage of the coating over
extended periods. It ensures that the coating is homogeneous and ready for
application with the minimum of agitation. It also con-trols the flow
properties of the coating and is designed to suit the application method that
is used The sus- pension agent makes up 1 to 5% of the coating.
When water is used as the
carrier liquid, bentonite clay is used as a suspension agent. Bentonite swells
and forms a gel when mixed with water. Time must be allowed for gelling to
proceed to completion. Two kinds of bentonite are in common use, one linked
with calcium and the other with sodium ions. As a suspension agent bentonites
ini-tially of the sodium type are preferred. Calcium bentonite is converted to
sodium bentonite by treatment with so-dium carbonate. This treatment affects
the swelling power of the clay and makes control of the viscosity of the
coat-ing unpredictable. Apart from the difficulties with quality control of the
bentonite, it has the disadvantage of tending to induce shrinkage cracks in the
coating when dried. In view of the drawbacks associated with bentonite,
substi-tutes are found in polysaccharide and certain forms of carboxymethyl
cellulose. Polysaccharides require special mixers, which few foundries possess,
to obtain optimum suspension The cellulose type does not require this special
mixers and do not induce shrinkage cracks as does dried bentonite as shown in Figure
4 below.
With organic
solvent-based carrier systems, different suspension agents are used. Modified
bentonite known also as organic bentonite or bentone will gel and increase the
viscosity of organic liquids such as alcohols and sol- vents. Bentones result
from a base exchange of the inor-ganic Ca and Na cation for an organic one
which is qua-ternary ammonium. Examples of suitable suspension agent for
organic solvent-based carrier are hydrogenated castor oil and quaternary alkyl
ammonium montmorillo-nite gels
3.4. Binding Agents
Binding agents are
various materials which act to hold the particles of refractories together and
attach them to the sand surface. The quantity of binder required for this
purpose increases a little as the particle size of the re-fractory decreases,
thereby increasing the surface area for a given ratio in the coating. However,
it makes up to 1 to 5% of the coating. It is important to determine the
mini-mum quantity of the binding agent, because too little results in poor
adhesion but, excess produces brittle coating which may crack on drying and
spall off during casting. Furthermore, resins and similar organic binders
evolve gas on heating. Thus, any undispersed binder col-lected in partially
dried areas of moulds or cores will cause local concentration of gas
generation. In this way, defects such as porosity and lapping can result. It is
also worthy to note that most organic binders and many sus-pension agents used
in water suspensions are subject to biological degradation. For longer storage of
the coating, precautions must be taken to suppress these reactions. Such
reactions do not occur with spirit-based coatings. Binders used for water
suspensions include sulphite lye, various clays (bentonite and kaolin),
dextrin, molas-ses, sugars, silica ester and resins (furan and phenol) soluble
or miscible with water. For spirit-based suspen-sions, natural or synthetic
resins are required. These in-clude furan, phenol, urea formaldehyde, phenol
formal-dehyde, novolac and natural wood resins.
4. Coating Application
Methods
Several variables
dictate the choice of application method. Part geometry and size, appearance of
the coating finish, and production rate, allinfluence the type of application
method. Facility constraints will also determine the choice of application
method. The configuration of the applica-tion equipment is dependent on space
or climate. Systems can be manually or automatically controlled. Other sys-tems
may require extra equipment, such as holding tanks or outside air supply to
operate properly.
Similar
application systems may operate at widely varying parameters. The viscosity of
the coating material, the desired thickness of the final coating, and the
com-plexity of the part will determine the best operating-parameters for the
application method. Thus, part tem-peratures, dip times or number of coats are
put into con-sideration.
One factor that is
important to all application methods is the transfer efficiency of coating
material onto the part. Transfer efficiency is the percentage of solid coating
material used that actually deposited on the surface of the part. The amount of
solvent in the coating material is irrelevant. The higher the transfer
efficiency, the better, as more coating material adheres to the part and less
is wasted. Transfer efficiency ranges from 25% to 40% for conventional spray
systems to almost 100% for dip and powder coating methods. Much of the
pollution and waste created from organic finishing operations can be mini-mized
or eliminated by improving the transfer efficiency of the application system.
If the transfer efficiency cannot be improved, pollution control technology and
waste handling measures must be employed . The following are different methods
of applying foundry coating on cores or moulds.
1) Brushing and swabbing
2) Spraying
3) Dip coating
4) Flow coating
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